| Name | Nationality | Seasons |
|---|---|---|
| Unknown | 1906-1927 | |
| Félix Gila | Spain | 1927–1928 |
| Woggenhuber | Hungary | 1928–1929 |
| Félix Gila | Spain | 1929–1933 |
| José Planas | Spain | 1933–1934 |
| Fernando Fariña | Spain | 1933–1934 |
| José Torres | Spain | 1933–1936 |
| Hilario Marrero | Spain | 1939–1941 |
| Celso Mariño | Spain | 1941–1942 |
| Chacho | Spain | 1941–1943 |
| Ramón de la Fuente | Spain | 1943–1945 |
| Hilario Marrero | Spain | 1945–1946 |
| Juan Aurre Pérez | Spain | 1946–1947 |
| Luis Urquiri | Spain | 1947–1948 |
| Sabino Anfonegui | Spain | 1948–1949 |
| José Torres | Spain | 1948–1949 |
| Alejandro Scopelli | Argentina | 1949–1950 |
| Jerónimo "Oso" Díaz | Spain | 1950–1951 |
| Chacho | Spain | 1951–1952 |
| Fernando Fariña | Spain | 1952–1953 |
| Francisco Casal Rey | Spain | 1952–1953 |
| Helenio Herrera | Argentina- France | 1952–1953 |
| Eduardo Toba Muíño | Spain | 1952–1953 |
| Carlos Iturraspe Cuevas | Spain | 1953–1954 |
| Eduardo Toba Muíño | Spain | 1954–1955 |
| Rodrigo García Vizoso | Spain | 1955–1956 |
| Ángel Zubieta | Spain | 1955–1957 |
| Diego Villalonga | Spain | 1956–1957 |
| Roberto Rodríguez Ozores | Spain | 1957–1958 |
| Carlos Iturraspe Cuevas | Spain | 1957–1958 |
| Ernesto Pons | Spain | 1958–1959 |
| Hilario Marrero | Spain | 1958–1959 |
| Jesús Barrio Álvarez | Spain | 1959–1961 |
| Juan Ochoantozana Milicua | Spain | 1961–1962 |
| Enrique Rabassa | Spain | 1962–1963 |
| Rogelio Santiago | Spain | 1962–1963 |
| Roque Olsen | Argentina- Spain | 1963–1964 |
| Luis Carniglia | Argentina | 1964–1965 |
| Juan Ochoantozana Milicua | Spain | 1964–1965 |
| Rodrigo García Vizoso | Spain | 1964–1965 |
| Enrique Orizaola Velázquez | Spain | 1965–1967 |
| Dagoberto Moll | Uruguay | 1966–1967 |
| Pedro Eguiluz Lamarca | Spain | 1967–1968 |
| José María Martín Rodríguez | Spain | 1968–1969 |
| Roque Olsen | Argentina- Spain | 1970–1971 |
| Arsenio Iglesias | Spain | 1970–1973 |
| Fernando Riera | Chile | 1973–1974 |
| Carlos Torres Barallobre | Spain | 1973–1974 |
| Enrique Orizaola Velázquez | Spain | 1973–1974 |
| José A. Irulegui Germadia | Spain | 1974–1975 |
| José A. Naya Mella | Spain | 1975–1976 |
| José María Martín Rodríguez | Spain | 1975–1976 |
| Héctor Rial | Argentina- Spain | 1976–1977 |
| José María Martín Rodríguez | Spain | 1976–1977 |
| José Mª Sertucha | Spain | 1976–1977 |
| José López Rodríguez | Spain | 1976–1977 |
| Juan Arza | Spain | 1977–1978 |
| Enrique Mateos | Spain | 1978–1979 |
| Luis Suárez | Spain | 1978–1979 |
| Francisco J. García Verdugo | Spain | 1979–1980 |
| Joseíto | Spain | 1979–1980 |
| José Martínez Palomar | Spain | 1980–1982 |
| Luis Rodríguez Vaz | Spain | 1981–1982 |
| Arsenio Iglesias | Spain | 1982–1985 |
| Jesús Aranguren Merino | Spain | 1985–1986 |
| Eusebio Ríos | Spain | 1986–1988 |
| Arsenio Iglesias | Spain | 1988–1989 |
| Marco Antonio Boronat | Spain | 1989–1990 |
| Arsenio Iglesias | Spain | 1990–1991 |
| Marco Antonio Boronat | Spain | 1991–1992 |
| Arsenio Iglesias | Spain | 1991–1995 |
| John Toshack | Wales | 1995–1997 |
| Carlos Alberto Silva | Brazil | 1996–1998 |
| José Manuel Corral | Spain | 1997–1998 |
| Javier Irureta | Spain | 1998–2005 |
| Joaquín Caparrós | Spain | 2005–2007 |
| Miguel Ángel Lotina | Spain | 2007–present |